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1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE,DPPF

CAS：12150-46-8
MW：554.38
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1,1'-Bis(diphenylphosphino)ferrocene used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which i s a popular reagent for palladium-catalyzed coupling reactions.

Ligand for Pd-catalyzed cross-coupling.
Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.
Ligand for Ni-catalyzed amination of aryl chlorides.
Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles.
Ligand for Ni-catalyzed Suzuki reactions.
Ni-catalyzed hydroamination of 1,3-dienes.
Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.
Pd-catalyzed γ-arylation of β,γ-unsaturated ketones.
Ligand for Ru-catalyzed reduction of nitriles to primary amines.
Ligand for Rh-catalyzed alkyne head-to-tail dimerization.
Ligand for Rh-catalyzed cross-coupling
Ligand for Rh-catalyzed olefin isomerization
Ligand for Ni or Rh-catalyzed borylation
Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.